Variation of Crystallization Behavior in the Na2O-SiO2 Glasses by Heat Treatments.
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- WAKASUGI Takashi
- Dept. Chem. & Mater. Tech., Kyoto Inst. of Tech.
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- WEINBERG Michael C.
- Arizona Materials Laboratory, The Univ. of Arizona
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- OTA Rikuo
- Dept. Chem. & Mater. Tech., Kyoto Inst. of Tech.
Bibliographic Information
- Other Title
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- 熱処理によるNa2O‐SiO2系ガラスの結晶化挙動の変化
- ネツ ショリ ニ ヨル Na2O-SiO2ケイ ガラス ノ ケッショウカ キョドウ ノ ヘンカ
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Abstract
The crystallization behavior of Na2O-SiO2 glasses was studied by Differential Thermal Analysis(DTA). The crystallization peak temperature (TC) increased with an increase of SiO2 content. For the quenched glasses, homogeneous nucleation was dominant in the low SiO2 composition, while surface nucleation was dominant in the composition higher than 55mol%SiO2. The heat treatment at the temperatures between 653 and 773K reduced TC due to the nucleation during heat treatment. The decrease of TC corresponds to the increase of the number of nuclei in the glass sample for DTA measurement. The ratio of crystallization peak temperature to liquidus temperature was used to evaluate the thermal stability of glasses. It was found that this parameter was a good linear relationship with the critical cooling rate for glass formation.
Journal
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- Journal of the Society of Materials Science, Japan
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Journal of the Society of Materials Science, Japan 48 (6), 535-540, 1999
The Society of Materials Science, Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390001205393054976
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- NII Article ID
- 110002293779
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- NII Book ID
- AN00096175
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- ISSN
- 18807488
- 05145163
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- NDL BIB ID
- 4766671
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- Text Lang
- ja
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed