AlN共存下における立方晶BN焼結体の作製と性質

書誌事項

タイトル別名
  • Preparation and properties of cubic BN sintered compact with AlN.
  • AlN キョウゾンカ ニ オケル リッポウショウ BN ショウケツタイ ノ サ

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説明

Cubic BN was synthesized from hexagonal BN in the presence of AlN as a catalyst at high temperatures above 1000°C and pressures above 5.5GPa under controlled atmosphere. In order to protect AlN from oxidation during the high pressure and temperature treatment, the addition of benzene to the mixture of hex. BN and AlN was found to be more efficient than that of toluene. Fully dense cubic BN-AlN sintered compacts were fabricated simultaneously with the conversion of hex. BN at 6.5GPa and 1600°C. The Vickers microhardness of the sintered compact of 20mol% AlN-80mol% cubic BN was about 4500kg/mm2 at room temperature. Direct bonding of cubic BN grains was observed in the sintered compact.

収録刊行物

  • 材料

    材料 33 (374), 1355-1359, 1984

    公益社団法人 日本材料学会

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