書誌事項
- タイトル別名
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- The first experimental demonstration of thermal transformation of bacteriochlorophylls into benzoporphyrins in sediments
- バクテリオクロロフィル オ キゲン ト スル ベンゾポルフィリン ノ セイセイ ノ ケンショウ
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説明
Benzoporphyrins have been found as minor components of sedimentary porphyrins. It was proposed that benzoporphyrins were derived from bacteriochlorophylls c and d, which possess 3-methyl-4-n-propyl-, or 3-methyl-4-iso-butylpyrrole units. We established the diagenetic formation process of benzoporphyrins from these bacteriochlorophylls by heating experiments of model porphyrins (2,7,12,17-tetramethyl-3,8,13,18-tetra-n-propylporphyrin and 3,8,13,18-tetra-isobutyl-2, 7, 12, 17-tetramethylporphyrin). The heating products were oxidized by chromic acid to give phthalimides, in which the profile of phthalimides clearly indicates the formation of benzopyrrole units during heating experiments. These results imply that bacteriochlorophylls c and d are potential sources of benzoporphyrins found in petroleum and sedimentary rocks.
収録刊行物
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- Researches in Organic Geochemistry
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Researches in Organic Geochemistry 28 (0), 19-22, 2012
日本有機地球化学会
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詳細情報 詳細情報について
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- CRID
- 1390001205412626688
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- NII論文ID
- 110009593001
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- NII書誌ID
- AA11889471
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- ISSN
- 21897891
- 13449915
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- NDL書誌ID
- 024297413
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可
