CF/エポキシ複合材料の亜臨界水・超臨界メタノール処理から得られる回収炭素繊維の引張強度

書誌事項

タイトル別名
  • Tensile Strength of Carbon Fibers Reclaimed from CF/Epoxy Composite Using Subcritical Water and Supercritical Methanol
  • CF エポキシ フクゴウ ザイリョウ ノ アリンカイスイ チョウリンカイ メタノール ショリ カラ エラレル カイシュウ タンソ センイ ノ ヒッパリ キョウド

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抄録

Carbon-fiber reinforced epoxy was decomposed using subcritical water and supercritical methanol to reclaim carbon fibers. The tensile strength of the reclaimed carbon fibers was measured. Then SEM observation, XPS, and Raman spectral analysis were conducted to elucidate the change of tensile strength caused by decomposition. The tensile strength decreased by 6% in the case of decomposition with supercritical methanol, and by 12~17% with subcritical water. The surfaces of reclaimed carbon fibers were resin-free. Decomposition did not affect the fiber surface and fracture surface morphology. Subsequent XPS analysis revealed that functional groups of the carbon fiber surface had been removed. Raman spectral analysis showed decreased graphitization of the carbon fiber surface. These results imply that the fracture toughness of the carbon fiber surface decreased because of breakage of carbon-carbon bonds in the carbon fibers as a result of decomposition.

収録刊行物

  • 材料

    材料 59 (12), 964-969, 2010

    公益社団法人 日本材料学会

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