書誌事項
- タイトル別名
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- Synthesis of a Nanocomposites of Zr-Containing Nanoparticle/Poly(Ethylene Terephthalate) Via Polymerization
- ジルコニアケイ ナノ リュウシ ポリ エチレンテレフタレート ナノコンポジット ノ ジュウゴウ ニ ヨル ゴウセイ
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説明
The formation of nanoparticle-based nanocomposites of zirconium oxide/Poly (ethylene terephthalate) (ZrO-PET) during the polymerization process of PET was studied. Oxy zirconium compound was used as a precursor for the nanoparticles. This precursor was introduced to a ethylene therephthalate oligomer. ZrO nanoparticle-filled PET materials were obtained, when a heat treatment under low pressure condition was carried out. ZrO nanoparticles were in agglomerate condition in PET matrix. When the ratio of Cl/Zr in the starting precursor increases, particle size increases. From the structural analysis data, it was confirmed that the O/Zr ratio of the particles was almost unity, and its structure is differ from that of zirconia (zirconium oxide). It was also confirmed that the prepared particle had a structure with organic component. The thermal analysis indicated that ZrO-PET nanocomposites had two characteristic exothermic peaks observed on cooling. From the biaxial oriented film of ZrO-PET nanocomposites, an improvement of its tensile elongation break was confirmed.
収録刊行物
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- 材料
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材料 54 (4), 393-398, 2005
公益社団法人 日本材料学会
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詳細情報 詳細情報について
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- CRID
- 1390001205418832896
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- NII論文ID
- 110006266509
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- NII書誌ID
- AN00096175
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- ISSN
- 18807488
- 05145163
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- NDL書誌ID
- 7325054
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDLサーチ
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可
