Preparation of Benzoate/Terephthalate Mixed Cellulose Esters and PET-Grafted Cellulose
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- ISHII Daisuke
- Faculty of Sci. and Tech., Ryukoku Univ.
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- ITAHARA Kazuki
- Faculty of Sci. and Tech., Ryukoku Univ.
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- HAYASHI Hisao
- Faculty of Sci. and Tech., Ryukoku Univ.
Bibliographic Information
- Other Title
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- セルロースの安息香酸・テレフタル酸混合芳香族エステル化およびPETグラフト化
- セルロース ノ アンソク コウサン ・ テレフタルサン コンゴウ ホウコウゾク エステルカ オヨビ PET グラフトカ
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Description
Graft copolymerization of poly(ethylene terephthalate) (PET) to cellulose was attempted via esterification of cellulose with benzoyl chloride and terephthaloyl dichloride. The esterification of cellulose was performed in 8wt% LiCl/DMAc under reflux in N2 at 100°C using pyridine as basic catalyst. Cellulose benzoate terephtalate (CBT), further transformed to chloride form using thionyl chloride, was reacted with ethylene glycol and terephthaloyl dichloride in THF under reflux in N2 at 50°C using pyridine as basic catalyst. Formation of CBT and PET-grafted cellulose (PET-C) was suggested from FTIR spectra. PET-C showed melting transitions between 150 to 190°C and formed mesophase, in spite of the possible remaining of free PET chains.
Journal
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- Journal of the Society of Materials Science, Japan
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Journal of the Society of Materials Science, Japan 62 (4), 243-247, 2013
The Society of Materials Science, Japan
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Details 詳細情報について
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- CRID
- 1390001205445408256
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- NII Article ID
- 130003367161
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- NII Book ID
- AN00096175
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- ISSN
- 18807488
- 05145163
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- NDL BIB ID
- 024633560
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- Text Lang
- ja
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed