Synthesis, characterization and cross-linking reaction of poly(γ-benzyl-L-glutamate)-polyisoprene-poly(γ-benzyl-L-glutamate) triblock copolymers

  • Ochiai Bungo
    Department of Polymer Science and Engineering, Yamagata University.
  • Sato Daisuke
    Department of Polymer Science and Engineering, Yamagata University.
  • Nagai Atsushi
    Department of Polymer Chemistry,Graduate School of Engineering, Kyoto University. Molecular Engneering Institute,Kinki University
  • Endo Takeshi
    Molecular Engneering Institute,Kinki University

書誌事項

タイトル別名
  • <b>Synthesis, Characterization and Cross-linking Reaction of Poly(γ-Benzyl L-Glutamate)-Polyisoprene-Poly(γ -Benzyl-L-Glutamate) Triblock Copolymers </b>
  • Synthesis characterization and cross linking reaction of poly g benzyl L glutamate polyisoprene poly g benzyl L glutamate triblock copolymers

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説明

Triblock copolymers, poly(γ-benzyl-L-glutamate)-block-polyisoprene-block- poly(γ-benzyl-L-glutamate) (PBLG-b PI-b-PBLG), were prepared via the ring-opening polymerization of a N-carboxyanhydride of γ-benzyl-L-glutamate initiated with a diamino-terminated PI. Aggregate formation in solution was confirmed by dynamic light scattering measurement. The triblock copolymer was cross-linked via thermal polymerization of the double bond moieties in the PI segment. The phase separation behavior of the PBLG and PI segments was visualized by hydrolysis of the PBLG segment.

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