Ring-Opening Reaction of Epoxides with Amines in the Presence of Clays

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  • TSUJIMOTO Munekazu
    Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University
  • MATSUBARA Yoshio
    Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University
  • ASAKURA Jun-ichi
    I st Department of Biochemistry, School of Medicine, Kinki University
  • ITÔ Seisirô
    Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University
  • YOSHIHARA Masakuni
    Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University
  • MAESHIMA Toshihisa
    Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University

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Other Title
  • 粘土存在下におけるエポキシドとアミンとの反応
  • ネンド ソンザイカ ニ オケル エポキシド ト アミン ト ノ ハンノウ

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Description

The reaction of epoxides with amines in the presence of clays has been investigated. Ring-opening reactions were found to take place by using montmorillonite, bentonite or kaolin. The molar ratio.of products of SN1 and SN2 reactions varied depending on the combination of clay, epoxide and amine.

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