Kinetics of Electroless Formation of Copper Phthalocyanine Thin Films Using Surfactants with an Azobenzene Group

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  • ITO Yoshitaka
    Department of Chemistry and Materials Science, Tokyo Institute of Technology, Ohokayama
  • KAGA Yasumasa
    Department of Chemistry and Materials Science, Tokyo Institute of Technology, Ohokayama
  • SAJI Tetsuo
    Department of Chemistry and Materials Science, Tokyo Institute of Technology, Ohokayama

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  • アゾベンゼン修飾界面活性剤を用いた無電解法による銅フタロシアニン薄膜生成の速度論的検討
  • アゾベンゼン シュウショク カイメン カッセイザイ オ モチイタ ムデンカイホウ ニ ヨル ドウ フタロシアニン ハクマク セイセイ ノ ソクドロンテキ ケントウ

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Abstract

Kinetics of electroless formation of copper phthalocyanine (CuPc) thin film using redox-active surfactant with an azobenzene group (AZPEG) was studied. The amount of the deposited film depends on the mole fraction of AZPEG to mixed redox-inactive surfactant and hydrophile-liophile balance (HLB) value of the redox-inactive surfactant. The amount of the deposited film at optimum concentration of AZPEG decreases with HLB value of AZPEG. These phenomena were ascribed to the difference in the rate of desorption from the surface of the CuPc particle.

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