Polymer-Supported Terpyridine–Palladium Complex for the Aminocarbonylation in Water of Aryl Iodines Using Methoxylamine Hydrochloride as an Ammonia Equivalent

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  • Suzuka Toshimasa
    Department of Chemistry, Biology and Marine Science, University of the Ryukyus
  • Sueyoshi Hiromu
    Department of Chemistry, Biology and Marine Science, University of the Ryukyus
  • Ogihara Kazuhito
    Department of Chemistry, Biology and Marine Science, University of the Ryukyus

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  • Polymer-supported terpyridine–palladium complex for the aminocarbonylation in water of aryl iodides using methoxylamine hydrochloride as an ammonia equivalent

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<p>  A novel homogeneous transition-metal catalyst, a polymer-supported terpyridine–palladium(II) complex, was found to promote the aminocarbonylation of aryl iodines using methoxylamine under phosphine-free conditions in water with good yield. The catalyst was recovered and reused several times without loss of catalytic activity. To our knowledge, this is the first example of polymer-supported, palladium-catalyzed synthesis of primary amides by aminocarbonylation of aryl iodides and methoxylamine under phosphine-free conditions in water.</p>

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