Polymer-Supported Terpyridine–Palladium Complex for the Aminocarbonylation in Water of Aryl Iodines Using Methoxylamine Hydrochloride as an Ammonia Equivalent
-
- Suzuka Toshimasa
- Department of Chemistry, Biology and Marine Science, University of the Ryukyus
-
- Sueyoshi Hiromu
- Department of Chemistry, Biology and Marine Science, University of the Ryukyus
-
- Ogihara Kazuhito
- Department of Chemistry, Biology and Marine Science, University of the Ryukyus
Abstract
<p> A novel homogeneous transition-metal catalyst, a polymer-supported terpyridine–palladium(II) complex, was found to promote the aminocarbonylation of aryl iodines using methoxylamine under phosphine-free conditions in water with good yield. The catalyst was recovered and reused several times without loss of catalytic activity. To our knowledge, this is the first example of polymer-supported, palladium-catalyzed synthesis of primary amides by aminocarbonylation of aryl iodides and methoxylamine under phosphine-free conditions in water.</p>
Journal
-
- Transactions of the Materials Research Society of Japan
-
Transactions of the Materials Research Society of Japan 41 (3), 225-228, 2016
The Materials Research Society of Japan
- Tweet
Details
-
- CRID
- 1390001205514189312
-
- NII Article ID
- 130005263644
-
- ISSN
- 21881650
- 13823469
-
- Text Lang
- en
-
- Data Source
-
- JaLC
- Crossref
- CiNii Articles
- KAKEN
-
- Abstract License Flag
- Disallowed