Synthesis, Structures and Magnetic Properties of New Tris Nitroxide Radicals with the Triazine Ring

DOI

Bibliographic Information

Other Title
  • トリアジン骨格を有する新規トリスニトロキシドラジカルの合成、構造と磁気的性質

Abstract

Trisnitroxide radicals with the triazin ring were synthesized and their magnetic properties were studied. Synthesis of new trisnitroxide radicals 1(o-, m-, p-) which three phenyl nitronyl nitroxide moieties connected to the central triazine ring at their o-, m-and, p-position with ether bondong were attempted. Although hydroxyl amine precursor of m-, p-1 were given at moderate yields, theier oxidation by NaIO4 yielded not trisnitroxides. Temperature dependence of magnetic susceptibility on SQUID mesurement revieled that the main products were mononitroxides.

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Details 詳細情報について

  • CRID
    1390001205554172032
  • NII Article ID
    130004729085
  • DOI
    10.11494/kisoyuki.2010.0.1p30.0
  • Text Lang
    ja
  • Data Source
    • JaLC
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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