Electronic Structures of Nonalternant Carbocations with Benzofluorenyl Structures

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Other Title
  • ベンゾフルオレニル骨格をもつ非交互炭化水素カルボカチオンの電子構造

Description

A fluorenyl cation was reported to be antiaromatic, since its solvolysis was faster than triphenylmethyl cation. However recently the cation was suggested to be a triplet cation or a simple conjugated carbocation on the base of results by flash photolysis, solvolysis, and theoretical calculations. Therefore we now report investigation of benzofluorenyl cations by NMR and DFT calculations.

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Details 詳細情報について

  • CRID
    1390001205554254464
  • NII Article ID
    130004646408
  • DOI
    10.11494/kisoyuki.55.0.71.0
  • Data Source
    • JaLC
    • CiNii Articles
    • KAKEN
  • Abstract License Flag
    Disallowed

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