Reaction of Cyclic Silicon Compounds with C<SUB>60</SUB> in the Presence of Transition-Metal Complex

DOI

Bibliographic Information

Other Title
  • 遷移金属錯体を用いた環状ケイ素化合物とC<SUB>60</SUB>との反応

Description

It have been demonstrated that the facile silylation of fullerenes can be achieved with disiliranes, silylenes, and silyl radicals by photoreaction as reactive silicon species, which lower the oxidation potentials of fullerene derivatives due to the electron-donating property of organosilicon groups. On the other hand, it is well known that transition-metal complexes activate Si-Si bonds to react with unsaturated compounds. These fascinating results prompted us to investigate the validity of transition-metal complexes in silylation of fullerenes. Herein we report a novel silylation reaction of fullrenes catalyzed by transition-metal complexes. Thermal reactions of C60 and disiliranes in the presence of transition-metal complexes afforded 1:1 adducts of C60 and disiliranes.

Journal

Details 詳細情報について

  • CRID
    1390001205554519040
  • NII Article ID
    130004645680
  • DOI
    10.11494/kisoyuki.2011.0.181.0
  • Text Lang
    ja
  • Data Source
    • JaLC
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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