Regioselective Exohedral Functionalization of Endohedral Metallofullerene with Two Different Addendum
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- Sato Satoru
- University of Tsukuba, Center for Tsukuba Advanced Reserch Alliance
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- Maeda Yutaka
- Department of Chemistry, Tokyo Gakugei University
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- Inada Koji
- Department of Chemistry, Tokyo Gakugei University
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- Nikawa Hidefumi
- University of Tsukuba, Center for Tsukuba Advanced Reserch Alliance
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- Yamada Michio
- Department of Chemistry, Tokyo Gakugei University
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- Mizorogi Naomi
- University of Tsukuba, Center for Tsukuba Advanced Reserch Alliance
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- Hasegawa Tadashi
- Department of Chemistry, Tokyo Gakugei University
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- Tsuchiya Takahiro
- University of Tsukuba, Center for Tsukuba Advanced Reserch Alliance
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- Akasaka Takeshi
- University of Tsukuba, Center for Tsukuba Advanced Reserch Alliance
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- Kato Tatsuhisa
- Department of Chemistry, Josai University
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- Zdenek Slanina
- University of Tsukuba, Center for Tsukuba Advanced Reserch Alliance
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- Nagase Shigeru
- IMS
Bibliographic Information
- Other Title
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- 異なる2つの置換基を有する金属内包フラーレンの位置選択的合成
Description
The regioselective functionalization of La@C82 by two different groups was conducted. We chose 1,2,3,4,5-pentamethylcyclopentadiene (Cp*) and adamantylidene carbene (Ad:) as reactants because cyclopentadiene and Ad: afford the corresponding regioselective mono-adducts of La@C82, respectively. In this work, structural analysis of the mono-adduct of La@C82 with Cp* was also performed. The bis-adducts of La@C82 with Cp* and adamantylidene were synthesized by two different route and characterized. Furthermore, the addition position and the regioselectivity in functionalization of La@C82 derivatives were also discussed on the basis of spectroscopic analysis and theoretical calculation.
Journal
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- Abstracts of Symposium on Physical Organic Chemistry
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Abstracts of Symposium on Physical Organic Chemistry 2010 (0), A25-A25, 2011
The Society of Physical Organic Chemistry, Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390001205555448704
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- NII Article ID
- 130004729329
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- Text Lang
- ja
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- Data Source
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- JaLC
- CiNii Articles
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- Abstract License Flag
- Disallowed