Regioselective Exohedral Functionalization of Endohedral Metallofullerene with Two Different Addendum

DOI

Bibliographic Information

Other Title
  • 異なる2つの置換基を有する金属内包フラーレンの位置選択的合成

Description

The regioselective functionalization of La@C82 by two different groups was conducted. We chose 1,2,3,4,5-pentamethylcyclopentadiene (Cp*) and adamantylidene carbene (Ad:) as reactants because cyclopentadiene and Ad: afford the corresponding regioselective mono-adducts of La@C82, respectively. In this work, structural analysis of the mono-adduct of La@C82 with Cp* was also performed. The bis-adducts of La@C82 with Cp* and adamantylidene were synthesized by two different route and characterized. Furthermore, the addition position and the regioselectivity in functionalization of La@C82 derivatives were also discussed on the basis of spectroscopic analysis and theoretical calculation.

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Keywords

Details 詳細情報について

  • CRID
    1390001205555448704
  • NII Article ID
    130004729329
  • DOI
    10.11494/kisoyuki.2010.0.a25.0
  • Text Lang
    ja
  • Data Source
    • JaLC
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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