Preparation and Redox Properties of Aryl Substituted Quinoxalinoquinoxalines

DOI
  • Miura Youhei
    Department of Chemistry, Faculty of Science, Hokkaido University
  • Chiba Hiroshi
    Department of Chemistry, Graduate School of Science, Tohoku University
  • Kawai Hidetoshi
    Department of Chemistry, Faculty of Science, Hokkaido University PRESTO, Japan Science and Technology Agency
  • Fujiwara Kenshu
    Department of Chemistry, Faculty of Science, Hokkaido University
  • Suzuki Takanori
    Department of Chemistry, Faculty of Science, Hokkaido University

Bibliographic Information

Other Title
  • アリール基の置換したキノキサリノキノキサリン類縁体の合成と酸化還元特性

Description

Quinoxalinoquinoxaline is the nitrogen analogue of tetracene, which have attracting considerable attention from the viewpoints of electronic devices. We prepared the alkoxy and/or iode-substituted quinoxalinoquinoxalines and found that they exhibit high electrochemical amphotericity. We also found interesting properties of quinoxalinoquinoxaline analogues, such as high electron donating properties of dihydroquinoxalinoquinoxalines and semiconductivity of quinoxalinoquinoxalyl radicals. In this study, we have also prepared quinoxalinoquinoxalines with various aryl groups by using Suzuki coupling reaction, whose details will be also shown.

Journal

Keywords

Details 詳細情報について

  • CRID
    1390001205555926144
  • NII Article ID
    130004729180
  • DOI
    10.11494/kisoyuki.2010.0.2p43.0
  • Text Lang
    ja
  • Data Source
    • JaLC
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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