Role of Spacer Effects in Acyl Moiety on Unimolecular Dissociation for <I>N</I>-(3-Phenylpropanoyl)-1-azacycloalkan-2-ones and Their Analogues

DOI

Bibliographic Information

Other Title
  • <I>N</I>-(3-フェニルプロピオニル)ラクタム類縁体の気相単分子イオン分解 ―アシル鎖長のスペーサとしての役割―

Abstract

Metastable ion spectra for electron ionized molecular ions for titled N-(3-Phenylpropanoyl)-1-azacycloalkan-2-ones derivatives gave double hydrogen transferred ion and unusual product ions whose mass is M-57 during 3rd field free region by a four sector tandem mass spectrometer. These data reveal the origin for unusual gas phase unimolecular dissociation based on role of spacer effects in acyl moiety.

Journal

Details 詳細情報について

  • CRID
    1390001205556799744
  • NII Article ID
    130004645544
  • DOI
    10.11494/kisoyuki.2008.0.59.0
  • Text Lang
    ja
  • Data Source
    • JaLC
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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