Molecular Structure of Endohedral Metallofullerene Ce2@D5h-C80

DOI

Bibliographic Information

Other Title
  • 金属内包フラーレンCe2@ D5h-C80の分子構造

Description

Single crystal X-ray diffraction studies of Ce2@D5h-C80•NiII(OEP) (OEP = octaethylporphinate) reveal that the motion of Ce2 in D5h-C80 cage was nearly frozen at 90 K. Detailed analysis demonstrates that each Ce atom with major occupancy is approaching to a pyracylene unit of D5h-C80 cage with the Ce-C distance ranging from 2.287 Ǻ to 2.944 Ǻ. Therefore, it appears that the presence of the pracylene unit of D5h-C80 cage is crucial in freezing the motion of endohedral Ce2.

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Keywords

Details 詳細情報について

  • CRID
    1390001205556880256
  • NII Article ID
    130004645884
  • DOI
    10.11494/kisoyuki.2011.0.365.0
  • Text Lang
    ja
  • Data Source
    • JaLC
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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