Phosgene-free synthesis of aromatic urethane from carbon dioxide

DOI
  • Choi Jun-Chul
    National Institute of Advanced Industrial Science and Technology (AIST) University of Tsukuba
  • Yuan Haoyu
    University of Tsukuba
  • Onozawa Shun-ya
    National Institute of Advanced Industrial Science and Technology (AIST)
  • Fukaya Norihisa
    National Institute of Advanced Industrial Science and Technology (AIST)
  • Yasuda Hiroyuki
    National Institute of Advanced Industrial Science and Technology (AIST)

Bibliographic Information

Other Title
  • ホスゲンを用いない二酸化炭素からの芳香族ウレタン合成

Abstract

We developed the environmentally benign synthetic method of aromatic urethane from amine and carbon dioxide without toxic and corrosive phosgene.  Specifically, we have succeeded in the reaction of aniline and tin alkoxide in the presence of carbon dioxide (5 MPa) gave the corresponding aromatic urethane in the yields up to 80%.

Journal

Details 詳細情報について

  • CRID
    1390001205588260224
  • NII Article ID
    130005477552
  • DOI
    10.11523/sekiyu.2014f.0_46
  • Text Lang
    ja
  • Data Source
    • JaLC
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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