Characterization of the Mixed Proton-Electron Conductivity of Nanostructured Hydrous Ruthenium Oxides by Electrochemical Impedance Spectroscopy

DOI

Bibliographic Information

Other Title
  • 電気化学インピーダンス法による水和酸化ルテニウムナノ構造体のプロトン・電子混合導電性の評価

Abstract

Hydrous nanoparticulate and layered ruthenium oxides are candidates as high energy and high power electrochemical supercapacitor electrode materials. The mixed proton-electron conductivity of these hydrous materials has been postulated to be one of the reasons for the high energy capability. In this study, we explored the mixed conductivity of hydrous ruthenium oxides using electrochemical impedance spectroscopy and its relation with the supercapacitive behavior. The high capacitance of nanostructured hydrous ruthenium oxides was found to be due to the utilization of hydrated micropores and interlayer with the sacrifice of power capability. On the other hand, the variation in the electronic conductivity due to the change in water content or structure was insignificant.

Journal

Details 詳細情報について

  • CRID
    1390001205614370944
  • NII Article ID
    130006970499
  • DOI
    10.14853/pcersj.2006s.0.278.0
  • Data Source
    • JaLC
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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