PB48 アミノ酸イオン液体のデザイン性を利用した新しいリオトロピック液晶の構築(化学・材料,ポスター発表,2013年日本液晶学会討論会)

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書誌事項

タイトル別名
  • PB48 Novel lyotropic liquid-crystalline system based on high designability of amino acid ionic liquids

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説明

Amino acid ionic liquids(AAILs)are ionic liquids containing amino acids as component ions. We have found that some amphiphilic molecules show good compatibility with these AAILs and exhibit self-organization behavior in them. Instead of water, these AAILs were used as solvents to provide novel lyotropic liquid-crystalline systems whose self-organization behavior is designable. In this study, we examined the effect of amino acid anions on the self-organization behavior of amphiphilic molecules. We synthesized six AAILs and N-{3-[N,N-bis(2-hydroxyethyl)aminopropyl]}-3,4-didodecyloxy benzoylamide (1) as an amphiphilic molecule. By mixing these AAILs andamphiphile 1, we succeeded in the preparation of lyotropic liquid-crystalline (LC) systems exhibiting smectic, bicontinuous cubic and hexagonal columnar LC phases depending on the molar ratio.

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詳細情報 詳細情報について

  • CRID
    1390001205685660672
  • NII論文ID
    110009899310
  • DOI
    10.11538/ekitou.2013.0__pb48
  • ISSN
    24325988
    18803490
  • 本文言語コード
    ja
  • データソース種別
    • JaLC
    • CiNii Articles
  • 抄録ライセンスフラグ
    使用不可

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