31. A Study on the Estimation of True Rate Parameters of Coal Pyrolysis

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Other Title
  • 31.石炭の真の熱分解反応速度パラメータの評価法に関する考察

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Description

We have recently presented a new and simple method to estimate the rate parameters of coal pyrolysis reactions using the so-called Distributed-Activation-Energy-Model (DAEM). Using the new DAEM, we analyzed the weight loss curves measured at three different heating rates under a vacuum, 0.1Mpa, and 5Mpa. It was found that the pyrolysis pressure apparently affects the rate parameters, the distribution of activation energy, f (E), and the frequency factor, k_0 (E). The effect was interestingly coal rank dependent. Based on these results discussion was made on a means to estimate true rate parameters of coal pyrolysis reactions.

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Details 詳細情報について

  • CRID
    1390001205770282368
  • NII Article ID
    110006857273
  • DOI
    10.20550/jiesekitanronbun.36.0_123
  • ISSN
    24238309
    24238295
  • Text Lang
    ja
  • Data Source
    • JaLC
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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