No.1 褐鉄鉱を用いるタール中窒素の分解除去 : 褐鉄鉱のピリジン分解性能に及ぼす共存ガスの影響(改質・処理・クリーン化(1)、熱分解・コークス(1))
書誌事項
- タイトル別名
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- No.1 Catalytic Decomposition of Tar Nitrogen with Limonite : Effect of the Kind of Coexisting Gas on the Activity of Limonite Catalyst in Pyridine Decomposition
抄録
Catalytic performance of α-FeOOH-rich limonite in the decomposition of 100 ppmv pyridine (C_5H_5N) in different atmospheres under a large space velocity of 51000 h^<-1> has been investigated with a fixed bed quartz reactor to develop a novel hot gas cleanup method of removing the nitrogen in tar as N_2. The limonite catalyst achieves the almost complete decomposition of C_5H_5N in He at 500-750℃ and gives high N_2 yield of more than 80% at least for 10h at 500℃. The limonite is seriously deactivated by cofeeding syngas (20% CO/10% H_2) with C_5H_5N because of carbon deposition from CO. On the other hand, the addition of 10% CO_2 to the syngas improves the catalytic activity and restores the yield at 750℃ to ≥ 80% without carbon deposition.
収録刊行物
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- 石炭科学会議発表論文集
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石炭科学会議発表論文集 51 (0), 2-3, 2014
一般社団法人 日本エネルギー学会
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詳細情報 詳細情報について
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- CRID
- 1390001205770822656
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- NII論文ID
- 110009926045
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- ISSN
- 24238309
- 24238295
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可