4-4-2 窒化ホウ素を用いたアンモニアボラン合成法の開発(Session 4-4 水素製造・貯蔵 2)

DOI

書誌事項

タイトル別名
  • 4-4-2 Development of ammonia borane synthesis method using boron nitride

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説明

Ammonia borane (AB) is simply regenerated by using hydrazine and ammonia. This technique enables conversion of AB from hexagonal boron nitride (h-BN), which is activated by milling under hydrogen pressure. The conversion mechanism was clarified as B-H bonds on the h-BN surface created by ball-milling under hydrogen pressure forms AB. Since all reactions proceed on the h-BN surface, maximizing B-H surface by breaking of B3N3 ring structure is the key issue to increase conversion purity of AB.

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詳細情報 詳細情報について

  • CRID
    1390001205812423680
  • NII論文ID
    110009891913
  • DOI
    10.20550/jietaikaiyoushi.23.0_188
  • ISSN
    24238325
    24238317
  • 本文言語コード
    ja
  • データソース種別
    • JaLC
    • CiNii Articles
  • 抄録ライセンスフラグ
    使用不可

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