Growth of Multi-wall Carbon Nanotubes in RF Plasma(<Special Issue>Growth of Carbon Nanotubes and Their Applications
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- Koshio Akira
- Department of Chemistry for Materials, Faculty of Engineering, Mie University
Bibliographic Information
- Other Title
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- RFプラズマ中で成長する多層カーボンナノチューブ(<小特集>カーボンナノチューブの成長とその応用)
- RFプラズマ中で成長する多層カーボンナノチューブ
- RF プラズマ チュウ デ セイチョウ スル タソウ カーボンナノチューブ
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Description
The d-CNTs were produced by direct-vaporization of graphite without metal catalyst, using radio-frequency (RF) plasma. They were quite high in purity. The d-CNTs are multi-wall CNTs packed densely toward the center, and the innermost tubes have a diameter of 0.4nm, the smallest diameter possible for a single-wall carbon nanotube. All of them had acute tips with a cone angle of 19.2°. We observed that most of these d-CNTs became hollow after heat treatment at more than 2200℃ in vacuum. The inner diameter of the hollow multi-wall CNTs formed by heat treatment of the d-CNTs was about 3nm. We deduce that the inner nanotubes narrower than about 3 nm decomposed faster than the outer nanotubes did because the inner tubes had more structural stress due to their small diameters. This enables us to strictly control the outer and inner diameters of CNTs.
Journal
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- Journal of the Japanese Association for Crystal Growth
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Journal of the Japanese Association for Crystal Growth 30 (4), 300-305, 2003
The Japanese Association for Crystal Growth
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Details 詳細情報について
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- CRID
- 1390001205897151616
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- NII Article ID
- 110002715983
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- NII Book ID
- AN00188386
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- ISSN
- 21878366
- 03856275
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- HANDLE
- 10076/8577
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- NDL BIB ID
- 6684982
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- Text Lang
- ja
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- Data Source
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- JaLC
- IRDB
- NDL Search
- CiNii Articles
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- Abstract License Flag
- Disallowed