Polymerization of LC monomers built by intermolecular hydrogen bonding

DOI
  • MORI Toshimi
    Department of Applied Chemistry Biochemistry, Faculty of Engineering, Kumamoto University
  • KURIHARA Seiji
    Department of Applied Chemistry Biochemistry, Faculty of Engineering, Kumamoto University
  • NONAKA Takamasa
    Department of Applied Chemistry Biochemistry, Faculty of Engineering, Kumamoto University

Bibliographic Information

Other Title
  • 水素結合性液晶モノマーの構築と重合

Description

Benzoic acid derivative having vinyl group at the p-position through methylene spacer was synthesized Mixture of the benzoic acidderivative 4,4'-bipyridne (2:1 molar ratio) was found to show a smectic phase in the range of 89℃ to 113℃. Polymerization of the mixture was carried out by using 0.5wt% of 2,2-dimethoxy-2-phenyl-acetophenone as a photoradical imitator. Conversion of the mixture was more than 90% by UV irradiation for 5min at the smectic phase. The smectic phase was maintained after photopolyrrmerization.

Journal

Details 詳細情報について

  • CRID
    1390001206108385664
  • NII Article ID
    110001466625
  • DOI
    10.11538/ekitouyokou.23.0_30
  • ISSN
    24329959
    18803539
  • Text Lang
    ja
  • Data Source
    • JaLC
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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