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- 大野 浩章
- 大阪大学大学院薬学研究科
書誌事項
- タイトル別名
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- Development of Useful Reactions Based on the Novel Reactivities of Allenic Compounds and Their Application to Tandem Cyclizations
- アレンケイ カゴウブツ ノ アタラシイ ハンノウセイ ニ モトヅク ユウヨウ ハンノウ ノ カイハツ ト レンゾクカンカ ハンノウ エ ノ テンカイ
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This review highlights a recent study on allenic compounds by the author's group. In the first section, the organocopper-mediated ring-opening reaction of ethynylaziridines and palladium-catalyzed reductive synthesis of allenes are described. In the second section, palladium-catalyzed stereoselective cyclization of allenes, including the tandem reaction, leading to aziridines, pyrrolidines, benzoisoindoles, and cyclopropanes is presented. The final section reviews aziridination and medium-ring formation due to the intramolecular reaction of bromoallenes. The latter reaction is based on the author's recent discovery that bromoallenes can act as allylic dication equivalents in the presence of a palladium catalyst and alcohol.<br>
収録刊行物
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- 薬学雑誌
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薬学雑誌 125 (12), 899-925, 2005-12-01
公益社団法人 日本薬学会
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詳細情報 詳細情報について
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- CRID
- 1390001206126965376
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- NII論文ID
- 110004042077
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- NII書誌ID
- AN00284903
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- ISSN
- 13475231
- 00316903
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- NDL書誌ID
- 7751461
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可