書誌事項
- タイトル別名
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- Reactions of Bifunctional Carbons and Their Application
- 2カンノウセイ タンソ ノ ハンノウ オヨビ ソノ ゴウセイ カガク エ ノ
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説明
As are known by various sorts of the representative methylene type the bifunctional carbons, which signify the carbons linking two heterofunctional groups, have proved to furnish characteristic reactivities. That is to say, they can undergo easy substitution of their one-side group and receive insertion of unsatureted spieces into their one-side bond. The aim of author's investigation in this field was to develop basic reactions as well as new reagents which are useful for practicing organic chemists. This article is to review the work in this laboratory, which is constituted of numerous new reactions involving reduction, substitution, carbon-carbon bond formation, rearrangement, insertion, 1, 3-dipolar cycloaddition and so on, with development of new reagents such as formic acid-triethylamine azeotrope as a reducing agent, diazoalkane-generating agent and aromatic diazotategenerating agent. Application of the reactions to the syntheses of some physiologically active compounds is also briefly summarized.
収録刊行物
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- 薬学雑誌
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薬学雑誌 104 (3), 205-221, 1984
公益社団法人 日本薬学会
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キーワード
- bifunctional carbon
- catalytic hydrogenolysis
- formic acid reduction
- sodium borohydride reduction
- α-amidoalkylation
- N-alkylamidomethylation
- secondary aminomethylation
- primary aminomethylation
- ring closure
- β-lactam
- phenylthiomethylation
- decarboxylation reaction
- insertion reaction
- rearrangement reaction
- diazoalkane-generating agent
- aromatic diazotate-generating agent
- alkanesulfinate
- alkanesulfinyl chloride
- alkanesulfenyl chloride
- 1, 3-dipolar cycloaddition
- pyrrolizidine alkaloid
- formic acid-triethylamine azeotrope
詳細情報 詳細情報について
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- CRID
- 1390001206127286656
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- NII論文ID
- 110003650616
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- NII書誌ID
- AN00284903
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- ISSN
- 13475231
- 00316903
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- NDL書誌ID
- 2989630
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- データソース種別
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- JaLC
- NDL
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- 使用不可