フェニルアシレートとアミドのアシル基交換反応(第3報)非極性溶媒下におけるアセチル基転位反応の動力学的検討

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書誌事項

タイトル別名
  • Transacylation between Phenyl Acylates and Amides. III. Kinetic Studies on the Transacetylation in Inert Organic Solvents
  • フェニルアシレートとアミドのアシル基交換反応-3-非極性溶媒下におけるアセチル基転位反応の動力学的検討
  • フェニルアシレート ト アミド ノ アシルキ コウカン ハンノウ 3 ヒ キョ

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抄録

In the previous paper, the transacylation between substituted phenyl acylates and substituted benzamides in the molten state at high temperature was described. The transacetylation was examined in inert organic solvents under mild conditions, and the reaction order and the substituent effect were discussed according to kinetic data and Hammett's plots. It was found that the substituted benzamides were acetylated with pseudo first-order kinetics and the Hammett's plots were straight lines of slope (p)+1.19 (substituted phenyl acetates) and -0.68 (substituted benzamides).

収録刊行物

  • 薬学雑誌

    薬学雑誌 104 (1), 11-19, 1984

    公益社団法人 日本薬学会

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