書誌事項
- タイトル別名
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- Sulfation of Alcohols with Arylsulfuryl Chlorides. I. : Monosulfation of Monosaccharides
説明
The authors found that arylsulfuryl chlorides can be used as mild sulfating agents, and they are applied to the monosulfation of monosaccharides. Among the six kinds of arylsulfuryl chlorides used 2, 4, 6-trichlorophenylsulfuryl chloride showed a low reactivity, while the rest of five showed the similar degree of reactivity. Phenylsulfuryl chlorides (PSC) was found to be the most practical agent from economical and productive point of view. Monosulfation of five hexoses and four pentoses with PSC under a suitable reaction condition (monosaccharide : PSC : pyridine=1 : 1 : 1 in molar ratio at 25° for 8hr.) gave only monosulfates of the primary hydroxyls. This fact was confirmed by the studies of methylation as well as periodate oxidation.
収録刊行物
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- 薬学雑誌
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薬学雑誌 87 (10), 1248-1255, 1967
公益社団法人 日本薬学会
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詳細情報 詳細情報について
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- CRID
- 1390001206185282560
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- NII論文ID
- 130007280561
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- ISSN
- 13475231
- 00316903
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- データソース種別
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- JaLC
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可
