Chemical Ecology of Mesostigmatid Mites. : I Identification of Hydroxymethylnaphthoquinones from Uroactinia hirschmanni HIRAMATSU (Mesostigmata: Uropodidae)
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説明
The yellow hexane extract from Uroactinia hirschmanni HIRAMATSU (Acari: Mesostigmata) consisted of 2 compounds by GLC analysis, which gave the same molecular ion at m/z 188 with similar sets of fragment ions, and each of which was isolated by a preparative TLC. One was identified as plumbagin (5-hydroxy-2-methyl-1, 4-naphthoquinone) by GLC, GC/MS and NMR analyses using authentic compounds. The other was suggested to be its isomer from mass spectrum and was identified as 7-methyljuglone (5-hydroxy-7-methyl-1.4-naphthoquinone) by NMR spectrum. Glandular pores, responsible for emitting these naphthoquinones, were detected as black spots on the body surface, by dipping mites bodies in a Tollen's reagent (aqueous AgNO3-NH4OH). This study represents the first time these naphthoquinones have been demonstrated in such a time.
収録刊行物
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- Applied Entomology and Zoology
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Applied Entomology and Zoology 32 (1), 57-61, 1997
日本応用動物昆虫学会
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詳細情報 詳細情報について
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- CRID
- 1390001206243642368
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- NII論文ID
- 130003928605
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- ISSN
- 1347605X
- 00036862
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- 本文言語コード
- en
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- データソース種別
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- JaLC
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- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可