Surface Analysis of Al Alloys with X-ray Photoelectron and Auger Electron Spectroscopies

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  • X線光電子分光分析やオージェ電子分光分析を用いるAl合金の表面分析
  • Xセン コウデン コブン コウブンセキ ヤ オージェ デンシ ブン コウブンセキ オ モチイル Al ゴウキン ノ ヒョウメン ブンセキ

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Abstract

In this paper, X-ray photoelectron spectroscopy (XPS) and Auger electron spectroscopy (AES) were applied to investigate passive films formed on aluminum alloy in 0.5 kmol m－3 H3BO3/0.05 kmol m－3 Na2B4O7 with different metal cations. The metal cation is classified by metal cation hardness, X, which are calculated based on the concept of hard and soft acids and bases (HSAB) of the acid and base in Lewis’s rule. From XPS analysis, the metal cations with X＞4 were incorporated in passive films. The area-selected surface analysis of AES was also introduced.

Journal

  • Zairyo-to-Kankyo

    Zairyo-to-Kankyo 64 (7), 281-284, 2015

    Japan Society of Corrosion Engineering

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