Crystallization and Raman Spectra of Langasite-Type Phases in Glasses of La<sub>3</sub>Ga<sub>5</sub>GeO<sub>14</sub>–Ba<sub>3</sub>Ga<sub>2</sub>Ge<sub>4</sub>O<sub>14</sub> System

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  • Crystallization and Raman Spectra of Langasite-Type Phases in Glasses of La3Ga5GeO14-Ba3Ga2Ge4O14 System

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Crystallization of the langasite-type La3Ga5GeO14–Ba3Ga2Ge4O14 mixed crystals in the stoichiometric corresponding glasses was studied by differential thermal and X-ray diffraction analyses, and by Raman spectroscopy. Although the glasses used in this study were multicomponent systems (BaO–La2O3–Ga2O3–GeO2), the langasite-type phases were singly crystallized in the corresponding glasses. The Raman spectroscopic study revealed the structural similarity on the scale of short-range order between the langasite-type phase and the corresponding glasses. This also strongly suggested the coexistence of Ga and Ge with six-coordination in the gallogermanate glasses.

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