Effects of Domain Size on Physical Properties of a Thermotropic Liquid Crystalline Polyester.
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- Lyou Dong Jo
- Department of Chemical Engineering, Korea Advanced Institute of Science and Technology
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- Kim Sung Chul
- Department of Chemical Engineering, Korea Advanced Institute of Science and Technology
書誌事項
- タイトル別名
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- Effects of Domain Size on Physical Prop
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To see the effect of domain size on the physical properties of thermotropic liquid crystalline polyester, poly[(phenylsulfonyl)-p-phenylene 1,8-octamethylene bis(4-benzoate)] (NP8) having low isotropization temperature at 178°C, was synthesized via solution polymerization. Previous thermal histories were erased by treating at isotropic temperature at 200°C and the LC domain size was controlled by annealing at liquid crystal state temperature, at 170°C. LC domains grew with annealing time and the domain growth rate was scaled as d−t0.19 at 170°C. The effect of the LC domain size on the crystallization rate was investigated. Crystallization temperature of 110°C was chosen since the growth rate showed maximum at that temperature. Three crystal melting peaks were observed on the crystallized sample. Avrami treatment and WAXD analysis for the three different crystal structures revealed that the high temperature melting crystal has higher degree of orientation than the low temperature melting crystal. It was found that the NP8 with large domain size had the faster crystallization rate and higher isotropization temperature. The effect of domain size on the transient rheological properties showed that the larger domain size had smaller stress overshoot and N1 overshoot for the transient shear flow. The effect of domain size on the steady state rheological properties showed that the larger domain size had smaller steady state N1 values at low shear rate region.
収録刊行物
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- Polymer Journal
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Polymer Journal 29 (3), 279-285, 1997
The Society of Polymer Science, Japan
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詳細情報 詳細情報について
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- CRID
- 1390001206288125952
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- NII論文ID
- 10006271137
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- NII書誌ID
- AA00777013
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- COI
- 1:CAS:528:DyaK2sXhvFens7Y%3D
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- ISSN
- 13490540
- 00323896
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- NDL書誌ID
- 4163662
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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- 使用不可