Radicals of Diphenylbutadiynes and Their Interactions with Diphenylpicrylhydrazyl. A Suggestion for the Nontopochemical Polymerization Mechanism of Diacetylene.
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- Canizal Gerardo
- Instituto de Ciencias Nucleares, Universidad Nacional Autónoma de México
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- Burillo Guillermina
- Instituto de Ciencias Nucleares, Universidad Nacional Autónoma de México
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- Boldu Jose Luis
- Instituto de Física, Universidad Nacional Autónoma de México
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- Muñoz Eduardo
- Instituto de Física, Universidad Nacional Autónoma de México
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- Ogawa Takeshi
- Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México
書誌事項
- タイトル別名
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- Radicals of Diphenylbutadiynes and Thei
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Electron Spin Resonance studies of diarylbutadiynes such as diphenylbutadiyne and p,p′-butadiynylenedi(methyl benzoate) have shown that these compounds contain free radicals at room temperature and that the number of radicals in the solid state increases with temperature. The color of diphenylpicrylhydrazyl (DPPH) disappears when these diacetylenes are added, indicating that the stable DPPH radicals react with the diacetylenes. The results suggest a probable initiation mechanism of the polymerization of the diacetylenes which do not undergo topochemical polymerization.
収録刊行物
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- Polymer Journal
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Polymer Journal 29 (3), 230-233, 1997
The Society of Polymer Science, Japan
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詳細情報 詳細情報について
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- CRID
- 1390001206288138752
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- NII論文ID
- 10006270990
- 30001926452
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- NII書誌ID
- AA00777013
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- COI
- 1:CAS:528:DyaK2sXhvFensrc%3D
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- ISSN
- 13490540
- 00323896
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- NDL書誌ID
- 4163653
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可