The Polymerization of Methyl Methacrylate Using Cu(II) Benzamidinate Complexes

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  • Shibayama Koichi
    Minase Research Laboratories, R&D Institute, High Performance Plastics Company, Sekisui Chemical Co., Ltd. Graduate School of Science and Technology, Kumamoto University

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  • Polymerization of Methyl Methacrylate Using Cu 2 Benzamidinate Complexes

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Abstract

The polymerization of methyl methacrylate (MMA) by Cu(II) amidinate complexes in combination with alkyl aluminum complexes is reported. The preferred alkylating agent is methylaluminoxane (MAO) in terms of improved yield and catalyst activity. Mechanistic studies indicate that the active species is a copper(I) complex.

Journal

  • Polymer Journal

    Polymer Journal 35 (9), 711-713, 2003

    The Society of Polymer Science, Japan

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