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- Chen Chao-Lin
- Department of Chemical Engineering, National Kaohsiung University of Applied Sciences
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- Hsieh Tar-Hwa
- Department of Chemical Engineering, National Kaohsiung University of Applied Sciences
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- Ho Ko-Shan
- Department of Chemical Engineering, National Kaohsiung University of Applied Sciences
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説明
The degradation of Poly(vinylidene chloride-co-vinyl chloride) (VDC-VC copolymer) is found by the less order X-Ray diffraction patterns of annealed samples at 175°C. The degraded VDC-VC copolymer releases 1,3,5-trichlorobenzene, which behave as the nucleus of recrystallization during cooling and increase the crystallinity. The recrystallization behavior demonstrates that it is very sensitive to the degradation of VDC-VC copolymer. The degraded VDC-VC copolymer has an enhanced nucleation effect at lower temperature (90°C) resulting in higher crystallinity and rate of recrystallization regardless of better diffusion ability at higher temperatures. The polarized optical pictures reveal the growing of spherulites and the average size is about 2.9 mm.
収録刊行物
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- Polymer Journal
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Polymer Journal 33 (11), 835-841, 2001
The Society of Polymer Science, Japan
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詳細情報 詳細情報について
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- CRID
- 1390001206289101568
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- NII論文ID
- 130004430270
- 10010078094
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- NII書誌ID
- AA00777013
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- COI
- 1:CAS:528:DC%2BD3MXos1OhtLg%3D
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- ISSN
- 13490540
- 00323896
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- NDL書誌ID
- 5985147
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可