Mechanism of Anionic Polymerization of (Meth)acrylates in the Presenceof Aluminium Alkyls IV. Formation of a Co-ordinative Polymer Network via the Living Aluminate End Group.

DOI 参考文献11件

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説明

The polymerization of methyl methacrylate in the presence of aluminium alkyls in toluene deviates from conventional kinetics. This results predominantly from the formation and precipitation of a co-ordinative polymer gel or network. Due to the lower reactivity and accessibility of the living chains in the gel, they are regarded as ’dormant’ and thus the concentration of active species decreases during polymerization. The network formation occurs via co-ordination of the living aluminate chain end group with in-chain ester carbonyl groups. Part of the chains are deactivated by a termination process but they are free of cyclic β-ketoesters which would result from the common ’back-biting’ reaction.

収録刊行物

  • Polymer Journal

    Polymer Journal 28 (11), 954-959, 1996

    The Society of Polymer Science, Japan

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詳細情報 詳細情報について

  • CRID
    1390001206289967872
  • NII論文ID
    130004429726
  • DOI
    10.1295/polymj.28.954
  • COI
    1:CAS:528:DyaK28XmvFClur8%3D
  • ISSN
    13490540
    00323896
  • 本文言語コード
    en
  • データソース種別
    • JaLC
    • Crossref
    • CiNii Articles
  • 抄録ライセンスフラグ
    使用不可

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