Effects of Chemical Reactions on the Properties of Copolyesters Made from Poly(ethylene terephthalate) Prepolymer and Liquid Crystalline Polymer.
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- Hwang Chang Ik
- Department of Chemical Engineering, Korea Advanced Institute of Science & Technology
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- Park O Ok
- Department of Chemical Engineering, Korea Advanced Institute of Science & Technology
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説明
Copolyesters were prepared by melt-phase polycondensation of poly(ethylene terephthalate) (PET) prepolymer and a thermotropic liquid crystalline polymer (LCP), 60 mol% p-hydroxybenzoic acid and 40 mol % poly(ethylene terephthalate) (PHB60/PET40). The copolyesters were characterized using gel permeation chromatography (GPC), nuclear magnetic resonance (NMR), thermal analysis, and wide angle X-ray diffraction measurement. The molecular weights of final copolyesters decreased with the addition of LCP. GPC results indicate that chain scission reaction of LCP occurs accompanied by chain-growing reaction of PET. From NMR analysis, LCP added underwent transesterification resulting in statistical reorganization of chain sequence with producing ether type by-products responsible for limiting the chain growth of copolyesters. It was observed that the crystallization of PET was delayed and melting temperature decreased with increasing LCP content in copolyesters. The resulting thermal properties and structural regularities of copolyester can be modified by exchange reactions during preparation.
収録刊行物
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- Polymer Journal
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Polymer Journal 27 (3), 232-239, 1995
The Society of Polymer Science, Japan
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詳細情報 詳細情報について
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- CRID
- 1390001206290454144
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- NII論文ID
- 130004429637
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- COI
- 1:CAS:528:DyaK2MXksFCrsb0%3D
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- ISSN
- 13490540
- 00323896
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可