Polymerization of Sulfur-Containing Aldehydes. III. Copolymerization of Sulfur-Containing Aldehydes with Acetaldehyde and with n-Butyraldehyde

DOI 参考文献14件

書誌事項

公開日
1971
DOI
  • 10.1295/polymj.3.712
公開者
The Society of Polymer Science, Japan

この論文をさがす

説明

Copolymerizations of sulfur-containing aldehydes including β-methylthiopropaldehyde, β-methylthiobutyraldehyde, and β-ethylthiobutyraldehyde with acetaldehyde, as well as, with β-butyraldehyde, were carried out at −78°C in toluene using AlEt3 as an initiator. From the examination of the solubility, the composition, the infrared spectra, and the partial thermal decomposition of the resultant polymer, it was found that copolymerization with acetaldehyde yielded a random copolymer, while copolymerization with n-butyraldehyde produced the copolymer having block units. The facts were also supported by the determination of the apparent values of monomer reactivity ratios. The thermal stability of the copolymers was fairly good in comparison with the homopolymers of conventional higher aliphatic aldehydes.

収録刊行物

  • Polymer Journal

    Polymer Journal 3 (6), 712-716, 1971

    The Society of Polymer Science, Japan

参考文献 (14)*注記

もっと見る

キーワード

詳細情報 詳細情報について

  • CRID
    1390001206292000256
  • NII論文ID
    130004768778
  • DOI
    10.1295/polymj.3.712
  • ISSN
    13490540
    00323896
  • 本文言語コード
    en
  • データソース種別
    • JaLC
    • Crossref
    • CiNii Articles
  • 抄録ライセンスフラグ
    使用不可

問題の指摘

ページトップへ