Formation Pathway of Various Oxygenated Compounds for the Homogeneous Oxidation of Isopentane in the Vapor Phase.

DOI Web Site Web Site 15 References Open Access
  • NAGATA Hideo
    Chemical Engineering Gr., Dept. of Materials Process Engineering, Graduate School of Engineering, Kyushu University Dept. of Chemical and Biological Engineering, Sasebo National College of Technology
  • TASHIRO Shizuka
    Chemical Engineering Gr., Dept. of Materials Process Engineering, Graduate School of Engineering, Kyushu University
  • KISHIDA Masahiro
    Chemical Engineering Gr., Dept. of Materials Process Engineering, Graduate School of Engineering, Kyushu University
  • WAKABAYASHI Katsuhiko
    Chemical Engineering Gr., Dept. of Materials Process Engineering, Graduate School of Engineering, Kyushu University

Bibliographic Information

Other Title
  • イソペンタンの気相均一酸化反応による各種含酸素化合物の生成経路
  • イソペンタン ノ キソウキンイツサンカ ハンノウ ニ ヨル カクシュ ガン サンソ カゴウブツ ノ セイセイ ケイロ

Search this article

Description

The homogeneous oxidation of isopentane was investigated in the vapor phase. The main products were oxygenated compounds (3-methyltetrahydrofuran, 2-propyloxirane, 2-ethyl-2-methyloxirane, 2, 2, 3-trimethyloxirane, acetone and acetaldehyde) and isopentenes. The yields of oxygenated compounds and isopentenes depended on the residence time, indicating that the oxygenated compounds formed through isopentenes from isopentane. It is concluded from the results of the vapor-phase oxidation of isopentenes (3-methyl-1-butene, 2-methyl-2-butene and 2-methyl-1-butene) that 3-methyltetrahydrofuran and 2-propyloxirane might be formed through 3-methyl-1-butene, 2, 2, 3-trimethyloxirane and acetone through 2-methyl-2-butene, and 2-ethyl-2-methyloxirane through 2-methyl-1-butene in the vapor-phase oxidation of isopentane.

Journal

References(15)*help

See more

Keywords

Details 詳細情報について

Report a problem

Back to top