Thermoelectric Properties and Microstructure of (Zn0.98Al0.02)O Prepared by MA/HP Process
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- Suzuki Hiroaki
- Department of Materials Processing, Graduate School of Engineering, Tohoku University
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- Okamura Hiroshi
- Department of Materials Processing, Graduate School of Engineering, Tohoku University
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- Watanabe Ryuzo
- Department of Materials Processing, Graduate School of Engineering, Tohoku University
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説明
The (Zn0.98Al0.02)O ceramic is known to show high dimensionless figure of merit(ZT)at high temperature among the n-type oxide materials. But it has problem of the large lattice thermal conductivity compared with other thermoelectric materials. However the lattice thermal conductivity can be decreased by grain refining, and further improvement in the ZT value is possible. Thus we have tried to synthesize homogeneous (Zn0.98Al0.02)O powders with fine particles size by mechanical alloying(MA), and make the fine grained and dense (Zn0.98Al0.02)O ceramic under several sintering conditions, expeceting the increase of ZT value due to the decrease in lattice thermal conductivity. We found an optimum MA condition for grain refinement, but homogeneous (Zn0.98Al0.02)O powders could not be obtained under present MA conditions. The fine grained and dense (Zn0.98Al0.02)O ceramic obtained by MA/HP process shows the decrease in lattice thermal conductivity. Hot pressing was found to decrease the absolute value of Seebeck coefficient and increase the electrical conductivity as compared with the normal sintering (NS). MA/HP process will increase the amount of the substituted Al for Zn. The ZT value became the maximum by the MA/NS; ZT=0.13 at 1073K.
収録刊行物
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- 粉体および粉末冶金
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粉体および粉末冶金 50 (11), 937-943, 2003
一般社団法人 粉体粉末冶金協会
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詳細情報 詳細情報について
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- CRID
- 1390001206307538304
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- NII論文ID
- 10012549487
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- NII書誌ID
- AN00222724
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- ISSN
- 18809014
- 05328799
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- NDL書誌ID
- 6787151
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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