熱電変換材料  2段階焼結法で合成したNaCo2O4焼結体の微細構造と熱電特性

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  • Microstructures and Thermoelectric Properties of NaCo2O4 Prepared by Double-step Sintering.
  • 2 ダンカイ ショウケツホウ デ ゴウセイ シタ NaCo2O4 ショウケツタイ ノ ビサイ コウゾウ ト ネツデントクセイ

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The thermoelectric properties of sintered bodies of NaCo2O4, which is so far the most promising p-type candidate for oxide thermoelectric material, are investigated in terms of their sintering conditions. Double-step sintering, for which single-phase NaCo2O4 obtained by calcination and sintering with addition of 10% excess of Na each time is re-ground and sintered again, is revealed to attain a marked improvement in the thermoelectric performance of the oxide. The improvement is due to increase in both Seebeck coefficient and electrical conductivity, and is attributed to a distinct enhancement of the two-dimensionality in the crystallites constituting the sintered body. The oxide sintered body consequently attains the figure-of-merit of 0.88×10-3K-1 at 600°C, and the maximum ZT of 0.78 at 800°C.

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