Construction of Siloxane-based Porous Materials by Using Cage-type Element Blocks

  • SATO Naoto
    Faculty of Science and Engineering, Waseda University
  • WADA Hiroaki
    Faculty of Science and Engineering, Waseda University
  • SHIMOJIMA Atsushi
    Faculty of Science and Engineering, Waseda University
  • KURODA Kazuyuki
    Faculty of Science and Engineering, Waseda University Kagami Memorial Research Institute for Materials Science and Technology, Waseda University

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  • かご状元素ブロックを用いたシロキサン系多孔体の構築
  • カゴジョウ ゲンソ ブロック オ モチイタ シロキサンケイ タコウタイ ノ コウチク

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<p>Construction of nanoarchitectures using cage siloxane oligomers as element blocks is of much interest because of its excellent potential for creating novel porous materials. In this review, our recent work on the fabrication of siloxane-based nanostructures from cage siloxanes is presented. The arrangement of cage siloxanes units is controlled by various methods, including amphiphilic self-assembly and hydrogen bonding of silanol groups, toward the preparation of well-defined porous siloxane-based materials.</p>

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