Oxidation products of N-Methyl-2,2,7,8-tetramethyl-6-amino-chroman,a model compound of N-Methyl-γ-tocopheramine with Potassium Ferricyanide

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  • 五十嵐 脩
    Research Institute of Food Chemistry, Ochanomizu University

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  • Oxidation products of N-methyl-2,2,7,8-tetramethyl-6-amino-chroman, a model compound of N-methyl-.GAMMA.-tocopheramine with potassium ferricyanide.
  • Oxidation products of N Methyl 2 2 7 8

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N-Methyl-2, 2, 7, 8-tetramethyl-6-amino-chroman, a model compound of N-methyl-γ-tocopheramine, was submitted to an oxidation study with alkaline potassium ferricyanide. As oxidative products, 2, 2, 7, 8-tetramethyl-6-amino-chroman and dimeric (VI) were identified. Also, a trace of compound C which might be a azochroman was detected. It was concluded that an N radical formation is necessary to take the role of a biological antioxidant of N-methyl-γ-tocopheramine.

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