New Developments of Molecular Separation Technology by Porous Coordination Compounds

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  • Hosono Nobuhiko
    Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University
  • Kusaka Shinpei
    Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University
  • Matsuda Ryotaro
    Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University Department of Applied Chemistry, Graduate School of Engineering, Nagoya University PRESTO, Japan Science and Technology Agency

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Other Title
  • 多孔性金属錯体による分子分離技術の新展開
  • タコウセイ キンゾク サクタイ ニ ヨル ブンシ ブンリ ギジュツ ノ シン テンカイ

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Abstract

Technological needs for gas separation is being increased to date because of the environment and energy crisis of the current world. Porous coordination compounds (PCCs) or metal organic frameworks (MOFs) have recently attracted significant attention due to their potential in gas capture/separation applications. Their porous structures (e.g. pore and window sizes) as well as affinities to the gas molecules can be designed by the selection of chemical constituents (organic ligands and metal ions), which allow a variety of PCCs used for separations of various molecules in gas or liquid phase. In gas separation applications, PCCs have been used not only as adsorbents but also as solid membranes. Recently, PCC/polymer hybrid is emerging as a new strategy to realize PCC–based membranes with a sort of flexibility and processability. In this review, we highlight gas separation technique using PCCs and introduce emerging approaches towards PCC–based flexible membranes.

Journal

  • MEMBRANE

    MEMBRANE 41 (4), 160-164, 2016

    THE MEMBRANE SOCIETY OF JAPAN

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