サイズと組成で制御する多元半導体ナノ粒子の光機能

  • 亀山 達矢
    名古屋大学大学院工学研究科結晶材料工学専攻
  • 桑畑 進
    大阪大学大学院工学研究科応用化学専攻
  • 鳥本 司
    名古屋大学大学院工学研究科結晶材料工学専攻

書誌事項

タイトル別名
  • Controlling the Size and Chemical Composition of Multinary Semiconductor Nanocrystals for Improving Photochemical Functions
  • サイズ ト ソセイ デ セイギョ スル タゲン ハンドウタイ ナノ リュウシ ノ ヒカリ キノウ

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抄録

<p>Multinary I-III-VI2 group semiconductor nanocrystals, such as CuInS2, Cu(InGa)Se2, AgInS2 and their solid solutions with ZnS, have been attracting increasing attention due to their low toxicity, wide range of absorption from UV to visible or near-infrared regions, and tunable energy gap. In this review, we introduce recent progress of solution-phase syntheses of high-quality multinary nanocrystals, which are candidates for alternative materials of Cd- and Pb-based binary nanocrystals showing high toxicity. Physicochemical properties of multinary nanocrystals are tunable depending on their crystal size and chemical composition. For example, nanocrystals of solid solution between AgInS2 and ZnS exhibited strong photoluminescence, the color of which was controlled from red to green with an increase in the ZnS fraction. The controllability of their photochemical properties is useful to develop novel photofunctional materials for the applications, such as photocatalyst and biomolecule marker.</p>

収録刊行物

  • 表面科学

    表面科学 38 (1), 18-23, 2017

    公益社団法人 日本表面科学会

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