Identification of (+)-Phyllocladene, (-)-Sandaracopimaradiene, and (+)-Kaurene as New Fungal Metabolites from Fusicoccin-producing Phomopsis amygdali F6
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- KENMOKU Hiromichi
- Course of the Science of Bioresources, The United Graduate School of Agricultural Sciences, Iwate University (Yamagata University)
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- TANAKA Mio
- Department of Bioresource Engineering, Faculty of Agriculture, Yamagata University
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- OGIYAMA Koichi
- Department of Bioenvironment, Faculty of Agriculture, Yamagata University
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- KATO Nobuo
- Institute of Scientific and Industrial Research, Osaka University
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- SASSA Takeshi
- Course of the Science of Bioresources, The United Graduate School of Agricultural Sciences, Iwate University (Yamagata University) Department of Bioresource Engineering, Faculty of Agriculture, Yamagata University
Bibliographic Information
- Other Title
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- Identification of (+)-Phyllocladene, (−)-Sandaracopimaradiene, and (+)-Kaurene as New Fungal Metabolites from Fusicoccin-producing<i>Phomopsis amygdali</i>F6
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Abstract
A chemical analysis of the diterpene hydrocarbons produced by fusicoccin-producing fungus Phomopsis amygdali F6 identified five phyllocladene-related tri- and tetracyclic diterpene hydrocarbons. The presence of (+)-phyllocladene, (−)-sandaracopimaradiene, (+)-isopimara-8,15-diene, and (+)-pimara-8(14),15-diene in the fungus was demonstrated by GC-MS, 1H-NMR, and [α]D measurements. (+)-Kaurene was also identified by GC-MS and chiral capillary GC. The possible biosynthetic relationship of these metabolites is discussed.
Journal
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- Bioscience, Biotechnology, and Biochemistry
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Bioscience, Biotechnology, and Biochemistry 68 (7), 1574-1577, 2004
Japan Society for Bioscience, Biotechnology, and Agrochemistry
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Details 詳細情報について
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- CRID
- 1390001206475037312
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- NII Article ID
- 10013520244
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- NII Book ID
- AA10824164
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- ISSN
- 13476947
- 09168451
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- NDL BIB ID
- 7030948
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- PubMed
- 15277764
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- Text Lang
- en
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- Data Source
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- JaLC
- NDL
- Crossref
- PubMed
- CiNii Articles
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- Abstract License Flag
- Disallowed