Biogenesis of 2-Phenylethanol in Rose Flowers: Incorporation of [2H8]L-Phenylalanine into 2-Phenylethanol and its β-D-Glucopyranoside during the Flower Opening of Rosa 'Hoh-Jun' and Rosa damascena Mill
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- WATANABE Shuzo
- <i>The United Graduate School of Agricultural Science, Gifu University (Shizuoka University)</i>
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- HAYASHI Kentaro
- <i>Faculty of Agriculture, Shizuoka University</i>
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- YAGI Kensuke
- <i>Faculty of Agriculture, Shizuoka University</i>
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- ASAI Tatsuo
- <i>University Farm, Faculty of Agriculture, Shizuoka University</i>
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- MACTAVISH Hazel
- <i>Department of Agricultural Sciences, Imperial College at Wye, University of London</i> Present address: <i>ADAS Consulting Ltd.</i>
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- PICONE Joanne
- <i>Department of Agricultural Sciences, Imperial College at Wye, University of London</i>
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- TURNBULL Colin
- <i>Department of Agricultural Sciences, Imperial College at Wye, University of London</i>
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- WATANABE Naoharu
- <i>Faculty of Agriculture, Shizuoka University</i>
書誌事項
- タイトル別名
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- Biogenesis of 2-Phenylethanol in Rose Flowers: Incorporation of [2H8]L-Phenylalanine into 2-Phenylethanol and its .BETA.-D-Glucopyranoside during the Flower Opening of Rosa 'Hoh-Jun' and Rosa damascena Mill.
- Biogenesis of 2 Phenylethanol in Rose Flowers Incorporation of 2H8 L Phenylalanine into 2 Phenylethanol and its ベータ D Glucopyranoside during the Flower Opening of Rosa Hoh Jun and Rosa damascena Mill
- Biogenesis of 2-Phenylethanol in Rose Flowers: Incorporation of [<sup>2</sup>H<sub>8</sub>]<scp>L</scp>-Phenylalanine into 2-Phenylethanol and its β-<scp>D</scp>-…
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To clarify the biosynthetic pathway to 2-phenylethanol (2), the deuterium-labeled putative precursor, [2H8]L-phenylalanine ([2H8-1]), was fed to the flowers of Rosa ‘Hoh-Jun’ and R. damascena Mill. throughout maturation, ceasing feeding at the commencement of petal unfurling and at full bloom. Based on GC-MS analyses, [2H8]-1 was incorporated into both 2 and 2-phenylethyl β-D-glucopyranoside (3) when the flowers were fed until full bloom, whereas no such incorporation into 2 was apparent when feeding was ceased earlier. In both species of rose, the labeling pattern for 2 was almost identical to that for 3, and indicated the presence of [2H6]-, [2H7]- and [2H8]-2, and [2H6]-, [2H7]- and [2H8]-3. This may be ascribed to the equilibrium between 2 and 3. The labeling pattern for 2 and 3 also indicated that these compounds were produced from 1 via several routes, the route involving phenylpyruvic acid being the major one.)<br>
収録刊行物
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- Bioscience, Biotechnology, and Biochemistry
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Bioscience, Biotechnology, and Biochemistry 66 (5), 943-947, 2002
公益社団法人 日本農芸化学会
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詳細情報 詳細情報について
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- CRID
- 1390001206475460864
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- NII論文ID
- 110002693762
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- NII書誌ID
- AA10824164
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- COI
- 1:CAS:528:DC%2BD38XktlSkurY%3D
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- ISSN
- 13476947
- 09168451
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- NDL書誌ID
- 6179875
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- PubMed
- 12092844
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- PubMed
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可