Antioxidative Activities of Several Marine Polysaccharides Evaluated in a Phosphatidylcholine-liposomal Suspension and Organic Solvents.

  • XUE Changhu
    Department of Food Science and Technology, Faculty of Fisheries, Ocean University of Qingdao
  • YU Guangli
    Department of Food Science and Technology, Faculty of Fisheries, Ocean University of Qingdao
  • HIRATA Takashi
    Department of Fisheries, Faculty of Agriculture, Kyoto University
  • TERAO Junji
    National Food Research Institute, Ministry of Agriculture, Forestry and Fisheries
  • LIN Hong
    Department of Food Science and Technology, Faculty of Fisheries, Ocean University of Qingdao

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タイトル別名
  • Antioxidative Activities of Several Mar

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  The antioxidative activities of several water-soluble marine polysaccharides, alginate (ALG), alginate sulfate (SALG), propylene glucolalginate sodium sulfate (PSS), propylene glucol mannuronate sulfate (PGMS), the oligosaccharide of chitosan (OLC), N,O-carboxymethyl chitosan (NOCC) and hydroxypropylated chitosan (HPC), were examined in a phosphatidylcholine (PC)-liposomal suspension containing the water-soluble radical emitter, 2,2′-azobis (2-amidinopropane) dihydrochloride. In the suspensions containing OLC and SALG, the initial rates of PC-OOH accumulation were 2.78×10-8 Ms-1 and 2.88×10-8 Ms-1, respectively, while all the polysaccharides tested showed antioxidative activity.<br>   Liposoluble marine polysaccharides, hexanoyl chitin (HCH) and an N-benzoylhexanoyl chitosan (NBHC) solution, also retarded the hydroperoxide accumulation of methyl linoleate by effectively trapping peroxide radicals in organic solvents when the radical chain reaction had been initiated by 2,2′-azobis (2,4-dimethylvaleronitrile).<br>   The kinetic data presented indicate that the alginate and chitin derivatives can be expected to play a role in the antioxidative mechanism of biological systems.<br>

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