Characterization of Coupled-Zone in Sn-Cu Binary Eutectic Alloys Using Unidirectional Solidification

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  • Machida Junichi
    Department of Materials Science and Engineering, National Defense Academy
  • Esaka Hisao
    Department of Materials Science and Engineering, National Defense Academy
  • Tamura Manabu
    Department of Materials Science and Engineering, National Defense Academy
  • Shinozuka Kei
    Department of Materials Science and Engineering, National Defense Academy

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Other Title
  • 一方向凝固によるＳｎ‐Ｃｕ二元共晶系合金のカップルドゾーンの解明
  • 一方向凝固によるSn-Cu二元共晶系合金のカップルドゾーソの解明
  • 1ホウコウ ギョウコ ニ ヨル Sn Cu ニゲン キョウショウケイ ゴウキン ノ カップルドゾーソ ノ カイメイ

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  The Sn-Cu binary eutectic alloy is one of candidate alloys for lead-free solder. In order to investigate the evolution of solidified structure of Sn-Cu binary eutectic alloy, the unidirectional solidification technique has been applied using a Bridgman type furnace.<br>    Primary β-Sn exhibits dendrite morphology, on the other hand, a primary Cu6Sn5 indicates a faceted crystal, the cross section of which is typically H-shaped and eutectic structure is rod-like. Coupled growth zone of this alloy system is found to be extended to Cu-rich side and to be rather symmetric. This may be due to the difference in undercooling for growth of Cu6Sn5, β-Sn and eutectic phases. Jackson parameter of Cu6Sn5 is deduced to be high comparing with β-Sn.<br>

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